Molecular and Structural Formula
I. Definitions:
A. Structural Formula:
Shows the arrangement of atoms in a compound.
B. Molecular Formula:
Shows the number of atoms of each element in a compound.
II. Example:
n-Butane
- Structural formula: CH₃-CH₂-CH₂-CH₃
- Molecular formula: C₄H₁₀
III. Steps to Write Molecular Formula from Structural Formula:
- Identify different types of elements in the structural formula.
- Write symbols of these elements side by side.
- Count the number of atoms of each element.
- Show this number as subscripts for each element symbol.
IV. Example 6.13: Writing the Molecular Formula
Given structural formula: CH₃-CH₂-CH₂-OH
Molecular formula: C₃H₈O
V. Practice Exercise:
- Write molecular formulae for:
- CH₃-CH₂-OH
- CH₃-CH₂-NH₂
- CH₃-CO-CH₃
VI. Key Points:
- Chemistry: Science of materials of the universe
- Physical Chemistry: Deals with laws and theories of matter structure and changes
- Element: Substance with atoms of the same atomic number
- Compound: Two or more elements in fixed proportions held by chemical bonds
- Empirical Formula: Simplest whole-number ratio of atoms in a compound
- Molecular Formula: Exact number of atoms in a molecule
- Molecular Mass: Sum of atomic masses of all atoms in a molecule
- Avogadro's Number: Number of particles in one mole of a substance
- Mole: Amount of matter containing Avogadro's number of particles
- Gram Atomic Mass: Atomic mass in grams
- Gram Molecular Mass: Molecular mass in grams
- Gram Formula Mass: Formula mass in grams
VII. Additional References:
- Zumdahl, Introductory Chemistry
- Raymond Chang, Essential Chemistry
Note: This section covers the relationship between structural and molecular formulas, providing a method to derive molecular formulas from structural representations. It also summarizes key concepts in chemistry, emphasizing the importance of understanding molecular structure and composition.