Unit 06: Stoichiometry
I. Student Learning Outcomes (SLOs):
- State formulae of common elements and compounds
- Define molecular formula
- Define empirical formula
- Deduce formula and name of binary compounds from ions
- Deduce formula of molecular substances from given structures
- Use relationship: amount of substance = mass/molar mass
- Define mole and Avogadro's number
- Explain relationship between mole and Avogadro's constant
- Construct chemical and ionic equations
- Deduce symbol equations with state symbols
II. Introduction:
- Historical context: Ancient Greek philosophers' beliefs about elemental substances
- John Dalton's atomic theory in the 19th century
- 20th century developments in atomic structure
- Chapter goal: Understand fundamental concepts about matter
III. Empirical and Molecular Formulas:
A. Empirical Formula:
Definition: Simplest integer ratio of atoms of each element in a compound.
Example: Hydrogen peroxide (HO)
Exercise: Empirical formula of glucose
B. Molecular Formula:
Definition: Specifies the actual number of atoms of each element in one molecule.
Example: Hydrogen peroxide (H₂O₂), Glucose (C₆H₁₂O₆)
Relationship to empirical formula: Molecular formula is a multiple of the empirical formula.
Examples where empirical and molecular formulas are the same: H₂O (water), NH₃ (ammonia)
IV. Common Formulas:
Table of common elements and compounds with their formulas:
- Elements: Hydrogen (H₂), Oxygen (O₂), Nitrogen (N₂), etc.
- Compounds: Water (H₂O), Carbon dioxide (CO₂), Hydrochloric acid (HCl), etc.
V. Practice Exercises:
- Writing empirical formulas for carbon-hydrogen compounds
- Determining empirical and molecular formulas for aspirin, acetic acid, and caffeine
Note: This unit introduces basic concepts of chemical formulas and stoichiometry, providing a foundation for understanding chemical composition and reactions. It emphasizes the difference between empirical and molecular formulas and includes practical exercises for application of these concepts.