Periodic Table Empirical and Molecular Formulas: Periodicity

PlantUML Diagram

Unit 06: Stoichiometry

I. Student Learning Outcomes (SLOs):

  • State formulae of common elements and compounds
  • Define molecular formula
  • Define empirical formula
  • Deduce formula and name of binary compounds from ions
  • Deduce formula of molecular substances from given structures
  • Use relationship: amount of substance = mass/molar mass
  • Define mole and Avogadro's number
  • Explain relationship between mole and Avogadro's constant
  • Construct chemical and ionic equations
  • Deduce symbol equations with state symbols

II. Introduction:

  • Historical context: Ancient Greek philosophers' beliefs about elemental substances
  • John Dalton's atomic theory in the 19th century
  • 20th century developments in atomic structure
  • Chapter goal: Understand fundamental concepts about matter

III. Empirical and Molecular Formulas:

A. Empirical Formula:

Definition: Simplest integer ratio of atoms of each element in a compound.
Example: Hydrogen peroxide (HO)
Exercise: Empirical formula of glucose

B. Molecular Formula:

Definition: Specifies the actual number of atoms of each element in one molecule.
Example: Hydrogen peroxide (H₂O₂), Glucose (C₆H₁₂O₆)
Relationship to empirical formula: Molecular formula is a multiple of the empirical formula.
Examples where empirical and molecular formulas are the same: H₂O (water), NH₃ (ammonia)

IV. Common Formulas:

Table of common elements and compounds with their formulas:

  • Elements: Hydrogen (H₂), Oxygen (O₂), Nitrogen (N₂), etc.
  • Compounds: Water (H₂O), Carbon dioxide (CO₂), Hydrochloric acid (HCl), etc.

V. Practice Exercises:

  • Writing empirical formulas for carbon-hydrogen compounds
  • Determining empirical and molecular formulas for aspirin, acetic acid, and caffeine

Note: This unit introduces basic concepts of chemical formulas and stoichiometry, providing a foundation for understanding chemical composition and reactions. It emphasizes the difference between empirical and molecular formulas and includes practical exercises for application of these concepts.